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Corrosion Behavior of Nitrogen-Containing Low-Nickel Weld Cladding in KCl-MgCl<sub>2</sub> Eutectic Molten Salt at 900 °C
oleh: Taisen Yang, Yunhai Su, Zhiyong Dai, Yingdi Wang, Xuewei Liang, Zuyong Wei
Format: | Article |
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Diterbitkan: | MDPI AG 2022-12-01 |
Deskripsi
In this paper, the element nitrogen (N) is used to partially replace the element nickel (Ni) in flux-cored wire. A 44%Ni-24%Cr-0.18N nitrogen-containing low-nickel flux-cored wire with excellent corrosion resistance is prepared. The corrosion behavior of nitrogen-containing low-nickel weld cladding and Inconel 625 weld cladding in 40 KCl + 60 MgCl<sub>2</sub> (wt%) molten salt at 900 °C is studied. The results show that the selective dissolution of Cr occurs in both weld claddings. The corrosion resistance of the 44%Ni-24%Cr-0.18N nitrogen-containing low-nickel weld cladding is better than that of the Inconel 625 weld cladding. The reason is that added N can react with H<sup>+</sup> in molten salt to generate <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><msubsup><mrow><mi>NH</mi></mrow><mn>4</mn><mo>+</mo></msubsup></mrow></semantics></math></inline-formula>, remove corrosive impurities of MgOH<sup>+</sup> in molten salt and change the corrosion environment. N preferentially combines with Cr to form Cr<sub>2</sub>N, reduces the diffusion precipitation of Cr and improves the corrosion resistance.