Preparation of Colored Microcapsule Phase Change Materials with Colored SiO<sub>2</sub> Shell for Thermal Energy Storage and Their Application in Latex Paint Coating

oleh: Enpei Ma, Zhenghuang Wei, Cheng Lian, Yinping Zhou, Shichang Gan, Bin Xu

Format: Article
Diterbitkan: MDPI AG 2021-07-01

Deskripsi

This article reports the design and manufacture of colored microcapsules with specific functions and their application in architectural interior wall coating. Utilizing reactive dyes grafted SiO<sub>2</sub> shell to encapsulate paraffin through interfacial polymerization and chemical grafting methods, this experiment successfully synthesized paraffin@SiO<sub>2</sub> colored microcapsules. The observations of surface morphology demonstrated that the colored microcapsules had a regular spherical morphology and a well-defined core-shell structure. The analysis of XRD and FT-IR confirmed the presence of amorphous SiO<sub>2</sub> shell and the grafting reactive dyes, and the paraffin possessed high crystallinity. Compared with pristine paraffin, the thermal conductivity of paraffin@SiO<sub>2</sub> colored microcapsules was significantly enhanced. The results of DSC revealed that the paraffin@SiO<sub>2</sub> colored microcapsules performed high encapsulation efficiency and desirable latent heat storage capability. Besides, the examinations of UV-vis and TGA showed that the paraffin@SiO<sub>2</sub> colored microcapsules exhibited good thermal reliability, thermal stability, and UV protection property. The analysis of infrared imaging indicated that the prepared latex paint exhibited remarkable temperature-regulated property. Compared with normal interior wall coatings, the temperature was reduced by about 2.5 °C. With such incomparable features, the paraffin@SiO<sub>2</sub> colored microcapsules not only appeared well in their solar thermal energy storage and temperature-regulated property, but also make the colored latex paint coating have superb colored fixing capabilities.