Guanidinium 4-aminobenzoate

oleh: A. Matos Beja, J. A. Paixão, M. Ramos Silva, P. S. Pereira Silva

Format: Article
Diterbitkan: International Union of Crystallography 2010-03-01

Deskripsi

In the title compound, CH6N3+·C7H6NO2−, the cation and anion lie on crystallographic mirror planes. The 4-aminobenzoate anion is almost in a planar conformation with a maximum deviation of 0.024 (2) Å for the N atom. The bond length in the deprotonated carboxyl group is intermediate between those of normal single and double Csp2=O bonds, indicating delocalization of the charge over both O atoms of the COO− group. In the crystal, N—H...O hydrogen bonds assemble the ions in layers propagating in the bc plane. This structure is very similar to that of guanidinium benzoate.