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Marine environment provides a basic space for human survival and social sustainable development. The study of tribological problems and mechanism of marine engineering materials in the sea extreme environment has become one of key technologies to be developed urgently in the field of marine engineering. This review summarizes and analyzes the tribological research of key friction materials in marine environment, focuses on tribological properties of ceramic, polymer and metal, emphatically introduces the current situation and development trend of tribological research in marine environment, such as metal and metal pairs, ceramics and metal pairs, polymers and metal pairs, polymers and ceramic pairs, and aims to provide a tutorial reference for the selection and application of friction pairs of marine engineering equipment.