Spatiotemporal characterization of dissolved carbon for inland waters in semi-humid/semi-arid region, China

oleh: K. S. Song, S. Y. Zang, Y. Zhao, L. Li, J. Du, N. N. Zhang, X. D. Wang, T. T. Shao, Y. Guan, L. Liu

Format: Article
Diterbitkan: Copernicus Publications 2013-10-01

Deskripsi

Spatiotemporal variations of dissolved organic carbon (DOC) and inorganic carbon (DIC) in 26 waters across the semi-humid/semi-arid Songnen Plain, China, were examined with data collected during 2008–2011. Fresh (<i>n</i> = 14) and brackish (<i>n</i> = 12) waters were grouped according to electrical conductivity (threshold = 1000 μS cm<sup>&minus;1</sup>) Significant differences in the average DOC and DIC concentrations were observed between the fresh (5.63 mg L<sup>−1</sup>, 37.39 mg L<sup>&minus;1</sup>) and the brackish waters (15.33 mg L<sup>−1</sup>, 142.93 mg L<sup>&minus;1</sup>). Colored dissolved organic matter (CDOM) and DOC concentrations were mainly controlled by climatic–hydrologic conditions. The investigation indicated that the outflow conditions in the semi-arid region had condensed effects on the dissolved carbon, resulting in close relationships between salinity vs. DOC (<i>R</i><sup>2</sup> = 0.66), and salinity vs. DIC (<i>R</i><sup>2</sup> = 0.94). An independent data set collected in May 2012 also confirmed this finding (DOC: <i>R</i><sup>2</sup> = 0.79, DIC: <i>R</i><sup>2</sup> = 0.91), highlighting the potential of quantifying DOC and DIC via salinity measurements for waters dispersed in the plain. Indices based on the CDOM absorption spectra (e.g., the DOC-specific CDOM absorption (SUVA<sub>254</sub>), absorption ratio <i>a</i><sub>250</sub> : <i>a</i><sub>365</sub> (<i>E</i><sub>250</sub> : <i>E</i><sub>365</sub>) and the spectral slope ratio (Sr, <i>S</i><sub>275&minus;295</sub>/<i>S</i><sub>350&minus;400</sub>) were applied to characterize CDOM composition and quality. Our results indicate that high molecular weight CDOM fractions are more abundant in the fresh waters than the brackish waters.