Bis[μ-1,3-bis(4,5-dihydroimidazol-2-yl)benzene-κ2N:N′]bis[dichloridozinc(II)] N,N′-dimethylformamide disolvate
oleh: Gong Zhang, Yan-Yan Sun, Ya-Wen Zhang, Lin Cheng
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2008-10-01 |
Deskripsi
The title compound, [Zn2Cl4(C12H14N4)2]·2C3H7NO, is located on a centre of inversion with one half of a complex molecule and one dimethylformamide solvent molecule in the asymmetric unit. The ZnII ion is tetrahedrally coordinated by two organic ligands and two chloride ions. Each organic ligand acts as a bidentate ligand, connecting two ZnII ions, resulting in a dimeric [2:2] metallamacrocyclic structure. Adjacent molecules are further linked by N—H...Cl hydrogen bonds and the solvent is linked to the complex by N—H...O hydrogen bonds.