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Basal-Plane Catalytic Activity of Layered Metallic Transition Metal Ditellurides for the Hydrogen Evolution Reaction
oleh: Hagyeong Kwon, Dongyeon Bae, Hyeyoung Jun, Byungdo Ji, Dongyeun Won, Jun-Ho Lee, Young-Woo Son, Heejun Yang, Suyeon Cho
| Format: | Article |
|---|---|
| Diterbitkan: | MDPI AG 2020-04-01 |
Deskripsi
We report the electrochemical hydrogen evolution reaction (HER) of two-dimensional metallic transition metal dichalcogenides (TMDs). <i>TM</i>Te<sub>2</sub> (<i>TM</i>: Mo, W, and V) single crystals were synthesized and characterized by optical microscopy, X-ray diffraction, and electrochemical measurements. We found that <i>TM</i>Te<sub>2</sub> acts as a HER-active catalyst due to the inherent catalytic activity of its basal planes. Among the three metallic <i>TM</i>Te<sub>2</sub>, VTe<sub>2</sub> shows the best HER performance with an overpotential of 441 mV and a Tafel slope of 70 mV/dec. It is 668 mV and 137 mV/dec for MoTe<sub>2</sub> and 692 mV and 169 mV/dec for WTe<sub>2</sub>. Even though VTe<sub>2</sub> has the lowest values in the exchange current density, the active site density, and turn-over-frequency (TOF) among the three <i>TM</i>Te<sub>2</sub>, the lowest charge transfer resistance (R<sub>CT</sub>) of VTe<sub>2</sub> seems to be critical to achieving the best HER performance. First-principles calculations revealed that the basal-plane-active HER performance of metallic TMDs can be further enhanced with some Te vacancies. Our study paves the way to further study of the inherent catalytic activity of metallic 2D materials for active hydrogen production.