{&#956;-2-[(Benzothiazol-2-yl-2&#954;N)hydrazonomethyl-2&#954;N]-6-methoxyphenolato-1:2&#954;3O1,O6:O1}{2-[(benzothiazol-2-yl-1&#954;N)hydrazonomethyl-1&#954;N]-6-methoxyphenolato-1&#954;O1}(methanol-2&#954;O)(nitrato-2&#954;O)dicopper(II) nitrate

oleh: Yu-Ching Lin, Fung-E Hong

Format:	Article
Diterbitkan:	International Union of Crystallography 2009-09-01

Deskripsi

The title complex, [Cu2(C15H12N3O2S)2(NO3)(CH3OH)]NO3, has two CuII centres coordinated by two deprotonated 2-[(benzothiazol-2-yl)hydrazonomethyl]-6-methoxyphenol ligands, a methanol molecule and a nitrate ion. Both CuII centres are pentacoordinated in a distorted square-pyramidal fashion. The crystal structure is stabilized by N&#8212;H...O and O&#8212;H...O hydrogen bonds.

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{&amp;#956;-2-[(Benzothiazol-2-yl-2&amp;#954;N)hydrazonomethyl-2&amp;#954;N]-6-methoxyphenolato-1:2&amp;#954;3O1,O6:O1}{2-[(benzothiazol-2-yl-1&amp;#954;N)hydrazonomethyl-1&amp;#954;N]-6-methoxyphenolato-1&amp;#954;O1}(methanol-2&amp;#954;O)(nitrato-2&amp;#954;O)dicopper(II) nitrate

Deskripsi

{μ-2-[(Benzothiazol-2-yl-2κN)hydrazonomethyl-2κN]-6-methoxyphenolato-1:2κ3O1,O6:O1}{2-[(benzothiazol-2-yl-1κN)hydrazonomethyl-1κN]-6-methoxyphenolato-1κO1}(methanol-2κO)(nitrato-2κO)dicopper(II) nitrate