Photochemical diazidation of alkenes enabled by ligand-to-metal charge transfer and radical ligand transfer
oleh: Kang-Jie Bian, Shih-Chieh Kao, David Nemoto, Xiao-Wei Chen, Julian G. West
| Format: | Article |
|---|---|
| Diterbitkan: | Nature Portfolio 2022-12-01 |
Deskripsi
The difunctionalization of alkenes allows for efficient construction of molecular complexity. Combining Ligand-to-Metal Charge transfer (LMCT) and Radical Ligand Transfer (RLT), the authors show a photochemical diazidation using iron salts, allowing rapid preparation of vicinal diamines and other privileged synthetic motifs.