(μ-2,3-Dibromosuccinato-κ2O1:O4)bis[methanolato-κO)triphenylantimony(V)]
oleh: Li Quan, Handong Yin, Wenfu Fu
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2011-06-01 |
Deskripsi
In the title molecule, [Sb2(C6H5)6(C4H4Br2O4)(CH3O)2], two [Sb(CH3O)Ph3]+ units are linked by the two carboxylate O atoms of a meso-2,3-dibromosuccinate bridging ligand, forming a dinuclear compound. The SbIV atom is five-coordinated in a slightly distorted trigonal–bipyramid geometry by phenyl C atoms in the equatorial positions and two O atoms in the axial positions. C—H...O interactions link the molecules into a two-dimensional network parallel to (010). The —CH— group of the centrosymmetric 2,3-dibromosuccinate anion is disordered over two sites in a 0.6:0.4 ratio.