Highly efficient gold(I)-catalyzed Overman rearrangement in water
oleh: Dong Xing, Dan Yang
| Format: | Article |
|---|---|
| Diterbitkan: | Beilstein-Institut 2011-06-01 |
Deskripsi
A highly efficient gold(I)-catalyzed Overman rearrangement of allylic trichloroacetimidates to allylic trichloroacetamides in water is reported. With this environmentally benign and scalable protocol, a series of C3-alkyl substituted allylic trichloroacetamides were synthesized in good to high yields.