Tetraaquabis[5-(pyridin-4-yl)tetrazolido N5-oxide-κN2]manganese(II)

oleh: Xiang Jing, Ya Luo

Format: Article
Diterbitkan: International Union of Crystallography 2012-08-01

Deskripsi

The title compound, [Mn(C6H4N5O)2(H2O)4], is isotypic with its Zn, Ni and Cd analogues reported recently. In the crystal, the MnII cations are coordinated by four O atoms from four aqua ligands and two N atoms from two 5-(pyridin-4-yl)tetrazolide N5-oxide ligands in a distorted octahedral coordination environment. The asymmetric unit consists of one MnII cation located on a crystallographic twofold axis, and two crystallographically independent water molecules and one N-donor ligand in general positions. The discrete complex molecules are arranged in alternating rows parallel to [100] and are linked by O—H...N and O—H...O hydrogen bonds into a three-dimensional network.