[N-(3-Methoxy-2-oxidobenzylidene-κO2)leucinato-κ2N,O](1,10-phenanthroline-κ2N,N′)copper(II) monohydrate
oleh: Daqi Wang, Buqin Jing, Jianfang Dong, Lei Huang, Lianzhi Li
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2010-12-01 |
Deskripsi
The asymmetric unit of the title complex, [Cu(C14H17NO4)(C12H8N2)]·H2O, contains two independent CuII complex molecules and two uncoordinated water molecules. In each complex molecule, the Cu atom is O,N,O′-chelated by the tridentate Schiff base ligand and N,N′-chelated by the 1,10-phenanthroline ligand in a distorted square-pyramidal geometry. The Cu—N bond distances in the apical directions are 2.298 (4) and 2.268 (4) Å. In the crystal, intermolecular O—H...O and C—H...O hydrogen bonds together with C—H...π interactions result in a three-dimensional supramolecular structure.