Poly[(2,2′-bipyridine-κ2N,N′)(μ3-2,4,6-trimethylisophthalato-κ5O1,O1′:O1:O3,O3′)cadmium]
oleh: Shao-Gang Hou, Mei-Fang Jin
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2012-01-01 |
Deskripsi
In the crystal structure of the polymeric title complex, [Cd(C11H10O4)(C10H8N2)]n, the CdII cation is chelated by one 2,2-bipyridine ligand and two carboxyl groups from two trimethylisophthalate (TMIPA) anions, and is further coordinated by one carboxylate O atom from a third TMIPA anion, forming a distorted pentagonal–bipyramidal geometry. Each TMIPA anion bridges three CdII cations, forming polymeric complex sheets parallel to (001). Weak C—H...O hydrogen bonding occurs between adjacent sheets.