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In-situ Formation of Amorphous Co-Al-P Layer on CoAl Layered Double Hydroxide Nanoarray as Neutral Electrocatalysts for Hydrogen Evolution Reaction
oleh: Wanqing Teng, Zhaomei Sun, Zhaomei Sun, Junfeng Xie, Ziqiang Wang, Xiangjiang Zheng, Bo Tang
Format: | Article |
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Diterbitkan: | Frontiers Media S.A. 2020-10-01 |
Deskripsi
Exploration of high-efficiency and inexpensive electrode catalysts is of vital importance for the hydrogen evolution reaction (HER). In this research, an amorphous Co-Al-P layer was constructed on the surface of CoAl layered double hydroxide (CoAl-LDH) via an in-situ wet phosphidation strategy. The core-shell CoAl-LDH@Co-Al-P on Ti mesh (CoAl-LDH@Co-Al-P/TM) as an active HER electrocatalyst demands an overpotential of 150 mV to achieve a current density of 10 mA cm−2 at neutral pH. Moreover, CoAl-LDH@Co-Al-P/TM also exhibits good electrochemical stability and a superior Faradic efficiency of nearly 100%.