1-{(Z)-[3-(1-Hydroxyethyl)anilino]methylidene}naphthalen-2(1H)-one

oleh: Antar A. Abdelhamid, Shaaban K. Mohamed, Mehmet Akkurt, Peter N. Horton, Adel A. Marzouk

Format: Article
Diterbitkan: International Union of Crystallography 2013-01-01

Deskripsi

In the title compound, C19H17NO2, the dihedral angle between the benzene ring and the naphthalene ring system is 9.72 (5)°, while the torsion angle of the C—N—C—C bridging group is 179.24 (17)°. The methyl group of the 1-phenylethanol moiety is disordered over two positions with a refined occupancy ratio of 0.775 (5):0.225 (5). The molecular conformation is stabilized by an intramolecular N—H...O hydrogen bond, which generates an S(6) ring motif. In the crystal, molecules are linked by O—H...O hydrogen bonds, forming zigzag chains propagating along the c-axis direction. Neighbouring chains are linked via C—H...O interactions, forming a two-dimensional slab-like network parallel to the bc plane.