Semi-Hydrogenation of Acetylene to Ethylene Catalyzed by Bimetallic CuNi/ZSM-12 Catalysts

oleh: Song Hu, Chong Zhang, Mingyu Wu, Runping Ye, Depan Shi, Mujin Li, Peng Zhao, Rongbin Zhang, Gang Feng

Format: Article
Diterbitkan: MDPI AG 2022-09-01

Deskripsi

The purpose of this work is to develop a low-cost and high-performance catalyst for the selective catalytic hydrogenation of acetylene to ethylene. Non-precious metals Cu and Ni were selected as active ingredients for this study. Using ZSM-12 as a carrier, Cu-Ni bimetallic catalysts of CuNi<sub>x</sub>/ZSM-12 (x = 5, 7, 9, 11) with different Ni/Cu ratios were prepared by incipient wetness impregnation method. The total Cu and Ni loading were 2 wt%. Under the optimal reaction conditions, the acetylene conversion was 100%, and the ethylene selectivity was 82.48%. The CuNi<sub>7</sub>/ZSM-12 prepared in this work exhibits good performance in the semi-hydrogenation of acetylene to ethylene with low cost and has potential for industrial application.