Azo group-enabled metal- and oxidant-free alkenyl C–H thiolation: Access to stereodefined tetrasubstituted acyclic olefins
oleh: Hao-Jie Gao, Yu-Hang Miao, Shi-Kun Jia, Na Li, Li-Ping Xu, Wei Wang, Min-Can Wang, Guang-Jian Mei
| Format: | Article |
|---|---|
| Diterbitkan: | KeAi Communications Co. Ltd. 2023-02-01 |
Deskripsi
Metal- and oxidant-free alkenyl C–H thiolation enabled by the azo group had been established for the modular synthesis of tetrasubstituted acyclic olefins. The reaction was performed under mild reaction conditions with a broad substrate scope. The intramolecular 6-membered hydrogen-bonding network accounts for the observed excellent stereo-control.