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Palladium-Catalyzed Regioselective [3+2] Cycloadditions of <i>α</i>,<i>β</i>-Unsaturated Imines with Vinylethylene Carbonates: Access to Oxazolidines
oleh: Yuanbo Wang, Yue Wang, Tong Sun, Qinglin Liu, Er-Qing Li
Format: | Article |
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Diterbitkan: | MDPI AG 2024-08-01 |
Deskripsi
We reported palladium-catalyzed regioselective [3+2] cycloadditions of <i>α</i>,<i>β</i>-unsaturated imines with vinylethylene carbonates, providing the desired oxazolidines in moderate-to-high yields. This reaction provides a facile route for the highly regioselective synthesis of functional oxazolidines. The synthetic utility of the current method was also demonstrated by a gram-scale reaction.