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Preparation of Co<sub>3</sub>O<sub>4</sub> hollow nanospheres and gas sensing properties
oleh: KAN Kan, WANG Jue, FU Dong, Sementsov YURII, SONG Mei-hui, LIN Yu-fei, SHI Ke-ying
Format: | Article |
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Diterbitkan: | Journal of Materials Engineering 2019-01-01 |
Deskripsi
The porous Co<sub>3</sub>O<sub>4</sub> hollow nanospheres were synthesized <i>via</i> hard template method by a carbon spheres templated strategy. The morphology and structure of materials were studied by SEM, XRD, FTIR, BET and XPS. The structure and gas sensing properties of Co<sub>3</sub>O<sub>4</sub> hollow nanospheres were controlled by changing the concentration of precursor and aging time. The results show that the Co<sub>3</sub>O<sub>4</sub> hollow nanospheres with diameter of 500nm composed by 40nm Co<sub>3</sub>O<sub>4</sub> nanoparticles can be synthesized with 0.1mol/L precursor and aging for 48h. The surface of nanospheres is porous structure. The synthesized Co<sub>3</sub>O<sub>4</sub> hollow nanospheres sensor have good gas response to 100×10<sup>-6</sup>-0.5×10<sup>-6</sup> NH<sub>3</sub> at room temperature. The gas sensitivity to 100×10<sup>-6</sup> NH<sub>3</sub> reaches 155.8% and the response time is 1.3s. The limit level of this gas sensor to NH<sub>3</sub> is 0.5×10<sup>-6</sup>.