Evolution of thiolate-stabilized Ag nanoclusters from Ag-thiolate cluster intermediates

oleh: Yitao Cao, Jiahao Guo, Run Shi, Geoffrey I. N. Waterhouse, Jinheng Pan, Zhenxia Du, Qiaofeng Yao, Li-Zhu Wu, Chen-Ho Tung, Jianping Xie, Tierui Zhang

Format: Article
Diterbitkan: Nature Portfolio 2018-06-01

Deskripsi

Gold nanoclusters are known to grow stepwise from gold-thiolate monomers and oligomers. Here, the authors find that the evolution of silver nanoclusters differs completely from that of gold: rather than following a bottom-up pathway, the clusters evolve from similarly-sized Ag-thiolate cluster intermediates.