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In the crystal structure of the title compound, C6H8NO+·ClO4−·2H2O, intermolecular N—H...O and O—H...O hydrogen bonds occur. The protonated amine cations and the perchlorate anions are linked through the water molecules, and the hydroxy groups of the cations and the anions are linked through the water molecules. The cations are connected to the perchlorate anions via intermolecular N—H...O hydrogen bonds. In addition, the crystal structure exhibits weak intermolecular C—H...π interactions.