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He–Ar–S Isotopic Compositions of Polymetallic Sulphides from Hydrothermal Vent Fields along the Ultraslow-Spreading Southwest Indian Ridge and Their Geological Implications
oleh: Yan Wang, Zhongwei Wu, Xiaoming Sun, Xiguang Deng, Yao Guan, Li Xu, Yi Huang, Kaijun Cao
Format: | Article |
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Diterbitkan: | MDPI AG 2018-11-01 |
Deskripsi
Noble gases have become a powerful tool to constrain the origin and evolution of ore-forming fluids in seafloor hydrothermal systems. The aim of this study was to apply these tracers to understand the genesis of newly discovered polymetallic sulphide deposits along the ultraslow-spreading Southwest Indian Ridge (SWIR). The helium, argon, and sulphur isotope compositions of metal sulphide minerals were measured for a number of active/inactive vent fields in the Indian Ocean. The helium concentrations and isotopic ratios in these ore samples are variable (<sup>4</sup>He: 0.09⁻2.42 × 10<sup>−8</sup> cm<sup>3</sup>STP∙g<sup>−1</sup>; <sup>3</sup>He: 0.06⁻3.28 × 10<sup>−13</sup> cm<sup>3</sup>STP∙g<sup>−1</sup>; <sup>3</sup>He/<sup>4</sup>He: 1.12⁻9.67 R<sub>a</sub>) and generally greater than the modern atmosphere, but significantly lower than those in massive sulphides from the fast-spreading East Pacific Rise (EPR), especially for three Cu⁻Fe-rich samples from the ultramafic-hosted Tianzuo and Kairei vent fields. On the contrary, most of the SWIR sulphide deposits have somewhat higher <sup>40</sup>Ar/<sup>36</sup>Ar ratios of trapped fluids (ranging from 290.6 to 303.4) when compared to the EPR ore samples. Moreover, the majority of sulphide minerals from the Indian Ocean have much higher δ<sup>34</sup>S values (3.0‰⁻9.8‰, ~5.9 on average, <i>n</i> = 49) than other basaltic-hosted active hydrothermal systems on the EPR. Overall, these He⁻Ar⁻S results are well within the range of seafloor massive sulphide deposits at global sediment-starved mid-ocean ridges (MORs), lying between those of air-saturated water (ASW) and mid-ocean ridge basalt (MORB) end members. Therefore, our study suggests that the helium was derived mainly from the MORB mantle by degassing during the high-temperature stage of hydrothermal activity, as well as from a mixture of vent fluids with variable amounts of ambient seawater during either earlier or late-stage low-temperature hydrothermal episodes, whereas the argon in ore-forming fluids trapped within sulphide minerals was predominantly derived from deep-sea water. Additionally, relatively high δ<sup>34</sup>S values exhibit a great estimated proportion (up to nearly 40%) of seawater-derived components. In summary, sub-seafloor extensive fluid circulation, pervasive low-temperature alteration, shallow seawater entrainment, and mixing processes, may make a larger contribution to the SWIR hydrothermal ore-forming systems, compared to fast-spreading centres.