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Diaquabis(2-chlorobenzoato-κO)bis(N,N-diethylnicotinamide-κN1)nickel(II)
oleh: Hacali Necefoğlu, F. Elif Özbek, Barış Tercan, Hakan Dal, Tuncer Hökelek
Format: | Article |
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Diterbitkan: | International Union of Crystallography 2009-05-01 |
Deskripsi
In the monomeric and centrosymmetric title NiII complex, [Ni(C7H4ClO2)2(C10H14N2O)2(H2O)2], the NiII ion is located on an inversion center. The asymmetric unit contains one 2-chlorobenzoate ligand, one diethylnicotinamide (DENA) ligand and one coordinating water molecule, the ligands being monodentate. The four O atoms in the equatorial plane around the NiII ion form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by two N atoms of the DENA ligands in axial positions. The dihedral angle between the benzene ring and the attached carboxylate group is 87.36 (10)°, while the pyridine and benzene rings are oriented at an angle of 41.90 (5)°. In the crystal structure, intermolecular O—H...O hydrogen bonds link the molecules into a two-dimensional network parallel to (10overline{1}).