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Direct measurements of the colloidal Debye force
oleh: Hyang Mi Lee, Yong Woo Kim, Eun Min Go, Chetan Revadekar, Kyu Hwan Choi, Yumi Cho, Sang Kyu Kwak, Bum Jun Park
Format: | Article |
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Diterbitkan: | Nature Portfolio 2023-06-01 |
Deskripsi
Abstract Colloids often behave in a manner similar to their counterparts in molecular space and are used as model systems to understand molecular behavior. Here, we study like-charged colloidal attractions between a permanent dipole on an interfacial particle and its induced dipole on a water-immersed particle caused by diffuse layer polarization. We find that the scaling behavior of the measured dipole-induced dipole (D‒I) interaction via optical laser tweezers is in good agreement with that predicted from the molecular Debye interaction. The dipole character propagates to form aggregate chains. Using coarse-grained molecular dynamic simulations, we identify the separate roles of the D‒I attraction and the van der Waals attraction on aggregate formation. The D‒I attraction should be universal in a broad range of soft matter, such as colloids, polymers, clays, and biological materials, motivating researchers to further conduct in-depth research on these materials.