<i>N</i>-Cyclohexylcyclohexanaminium {[acetyl(methyl)amino]methyl}bis [4,5-dibromobenzene-1,2-diolato]silicate(IV) 4,5-dibrobenzene-1,2-diol Ethanol Solvate
oleh: Eugene P. Kramarova, Pavel V. Dorovatovskii, Anna V. Vologzhanina, Alexander A. Korlyukov
| Format: | Article |
|---|---|
| Diterbitkan: | MDPI AG 2023-01-01 |
Deskripsi
An X-ray diffraction study of a transesterification product of <i>N</i>-methyl-<i>N</i>-(trimethoxysilylmethyl)acetamide by 4,5-dibromobenzene-1,2-diol was carried out. It was established that the coordination polyhedron of the silicon atom in an anionic complex is a distorted octahedron disordered due to the superposition of the Δ and Λ optical isomers. The presence of various hydrogen donor groups in bis(cyclohexyl)ammonium cations, solvent ethanol molecules, and non-coordinated 4,5-dibromobenzene-1,2-diol caused the formation of H-bonded chains, while dibromobenzenediol also took part in stacking interactions.