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Coronoid systems actually arrangements of hexagons into six sides of benzenoids. By nature, it is an organic chemical structure. Hollow coronoids are primitive and catacondensed coronoids. It is also known as polycyclic conjugated hydrocarbons. The mathematical study of chemicals is of great interest to different specialties researchers. While graph theory always played a significant role to make chemical structures understandable and blessed with applications also. After transforming the chemical structure into a graph, one can implement different theoretical and implicative studies on structures. Metric dimension is considered as one of the most studied and implicative parameters of graph theory. In this concept, few suggested vertices are chosen such as the remaining vertices have unique locations or identifications. In this study, we discussed different metric-based parameters for the hollow coronoid structure.