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We analyze condensation behaviors of neutral scalar fields outside horizonless reflecting stars in the Einstein-Maxwell-scalar gravity. It was known that minimally coupled neutral scalar fields cannot exist outside horizonless reflecting stars. In this work, we consider non-minimal couplings between scalar fields and Maxwell fields, which is included to aim to trigger formations of scalar hairs. We analytically demonstrate that there is no hair theorem for small coupling parameters below a bound. For large coupling parameters above the bound, we numerically obtain regular scalar hairy configurations supported by horizonless reflecting stars.