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Fabrication, Optimization, and Performance of a TiO<sub>2</sub> Coated Bentonite Membrane for Produced Water Treatment: Effect of Grafting Time
oleh: Mohamad Izrin Mohamad Esham, Abdul Latif Ahmad, Mohd Hafiz Dzarfan Othman
Format: | Article |
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Diterbitkan: | MDPI AG 2021-09-01 |
Deskripsi
The main problem usually faced by commercial ceramic membranes in the treatment of produced water (PW) is low water flux even though ceramic membrane was well-known with their excellent mechanical, thermal, and chemical properties. In the process of minimizing the problem faced by commercial ceramic membranes, titanium dioxide (TiO<sub>2</sub>) nanocomposites, which synthesized via a sol-gel method, were deposited on the active layer of the hydrolysed bentonite membrane. This paper studied the influence of grafting time of TiO<sub>2</sub> nanocomposite on the properties and performance of the coated bentonite membranes. Several characterizations, which are Fourier transform infrared (FTIR), scanning electron microscopy (SEM), energy-dispersive X-ray Spectroscopy (EDX), contact angle, porosity, and average pore size, were applied to both pristine and coated bentonite membranes to compare the properties of the membranes. The deposition of TiO<sub>2</sub> nanoparticles on the surface of the coated bentonite membranes was successfully confirmed by the characterization results. The pure water flux performance showed an increment from 262.29 L h<sup>−1</sup> m<sup>−</sup>² bar<sup>−1</sup> (pristine bentonite membrane) to 337.05 L h<sup>−1</sup> m<sup>−</sup>² bar<sup>−1</sup> (Ti-Ben 30) and 438.33 L h<sup>−1</sup> m<sup>−</sup>² bar<sup>−1</sup> (Ti-Ben 60) as the grafting time increase but when the grafting time reached 90 min (Ti-Ben 90), the pure water flux was decreased to 214.22 L h<sup>−1</sup> m<sup>−</sup>² bar<sup>−1</sup> which is lower than the pristine membrane. The oil rejection performance also revealed an increase in the oil rejection performance from 95 to 99%. These findings can be a good example to further studies and exploit the advantages of modified ceramic membranes in PW treatment.