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Influence of 1n-transfer coupling on quasi-elastic scattering excitation function has been investigated for 6Li + 209Bi system. Coupled Reaction Channels Calculations have been carried out for the energies around the Coulomb barrier. Corresponding barrier distributions obtained with and without including 1n-transfer coupling, have been compared with experimental data. 1n-transfer effect on quasi-elastic excitation function has been observed to be insignificant for the present system. In the reaction of 6Li with 208Pb and 209Bi, an experimental relative contributions for breakup and 1n-transfer channels have been reproduced by simultaneous calculation using CDCC and CRC formalism.