Self-assembly of [2]Rotaxane Exploiting Reversible Pt(II)- Pyridine Coordinate Bonds
oleh: Rosa M. Gomila, Antoni Frontera, Pere M. DeyÃ, Antoni Costa, Magdalena Capó, Pablo Ballester
| Format: | Article |
|---|---|
| Diterbitkan: | MDPI AG 2004-04-01 |
Deskripsi
A dinuclear self-assembled cationic macrocycle based on Pt(II)-N(pyridine) coordinative bonds and having competitive triflate anions, as metal counterions, is used in the construction of [2]rotaxane and [2]pseudorotaxane architectures assisted by hydrogen bonding. The kinetic lability of the Pt(II)-N(pyridine) coordinative bond controls the dynamics of the [2]rotaxane.