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Continuous Emission Monitoring of Tetrafluoromethane Using Quantum Cascade Lasers
oleh: Peter Geiser, Viacheslav Avetisov, Luis Espinoza-Nava, Nicola Menegazzo, Peter Kaspersen
| Format: | Article |
|---|---|
| Diterbitkan: | MDPI AG 2016-04-01 |
Deskripsi
Recent developments in quantum cascade lasers have enabled the development of new sensors for in-situ applications that have so far only been possible with extractive systems. In this work, a sensor is presented using a unique Wavelength Modulation Spectroscopy approach to measure tetrafluoromethane, a strong greenhouse gas. The sensor was characterized in a laboratory environment indicating a long-term detection limit of 20 ppb·m and a short-term value of well below 10 ppb·m. To demonstrate the feasibility of the sensor in a real-world environment, it was installed at an Alcoa aluminum smelter. A co-located Fourier Transform Infrared Spectrometer allowed direct comparison measurements of both systems. General agreement between the two methods was observed, leading to the conclusion that the developed in-situ quantum cascade laser based sensor has the potential to continuously measure tetrafluoromethane at aluminum smelters.