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Dye-sensitized solar cells (DSSCs) are low-cost solar cells belonging to the thin-film photovoltaic cell type. In this study, we studied the photovoltaic performances of DSSCs based on titanium dioxide (TiO₂) nanofibers (NFs) containing silver (Ag) nanoparticles (NPs) under low illumination. We used the sol-gel method with the electrospinning technique to prepare the TiO₂ NFs containing Ag NPs. Herein, we used two ways to add TiO₂/Ag NFs to modify the photoelectrode successfully and enhance the performance of DSSCs. One way was that the TiO₂/Ag NFs were mixed with pristine TiO₂; the other way was that the TiO₂/Ag NFs were seeded beside the TiO₂ colloid layer as an additional layer on the photoelectrode of the DSSC. According to this experiment, the photovoltaic conversion efficiency of the DSSC which had TiO₂/Ag NF seeded as an additional layer on the photoelectrode (5.13%) was increased by 28% compared to the DSSC without the photoelectrode modification (3.99%). This was due to the suppression of electron recombination and the more effective utilization of the light radiation by adding the TiO₂/Ag NFs. Because of the good conductivity of Ag, the electrons were quickly transported and electron recombination was reduced. In addition, the photovoltaic conversion efficiency of the DSSC which had TiO₂/Ag NF seeded as an additional layer on the photoelectrode increased from 5.13% to 6.23% during the decrease in illumination from 100 mW/cm² to 30 mW/cm²; however, its photovoltaic conversion efficiency decreased to 5.31% when the illumination was lowered to 10 mW/cm².