Find in Library
Search millions of books, articles, and more
Indexed Open Access Databases
Applications of Long-Length Carbon Nano-Tube (L-CNT) as Conductive Materials in High Energy Density Pouch Type Lithium Ion Batteries
oleh: Shan-Ho Tsai, Ying-Ru Chen, Yi-Lin Tsou, Tseng-Lung Chang, Hong-Zheng Lai, Chi-Young Lee
Format: | Article |
---|---|
Diterbitkan: | MDPI AG 2020-06-01 |
Deskripsi
Lots of lithium ion battery (LIB) products contain lithium metal oxide LiNi<sub>5</sub>Co<sub>2</sub>Mn<sub>3</sub>O<sub>2</sub> (LNCM) as the positive electrode’s active material. The stable surface of this oxide results in high resistivity in the battery. For this reason, conductive carbon-based materials, including acetylene black and carbon black, become necessary components in electrodes. Recently, carbon nano-tube (CNT) has appeared as a popular choice for the conductive carbon in LIB. However, a large quantity of the conductive carbon, which cannot provide capacity as the active material, will decrease the energy density of batteries. The ultra-high cost of CNT, compared to conventional carbon black, is also a problem. In this work, we are going to introduce long-length carbon nano-tube s(L-CNT) into electrodes in order to design a reduced-amount conductive carbon electrode. The whole experiment will be done in a 1Ah commercial type pouch LIB. By decreasing conductive carbon as well as increasing the active material in the positive electrode, the energy density of the LNCM-based 1Ah pouch type LIB, with only 0.16% of L-CNT inside the LNCM positive electrode, could reach 224 Wh/kg and 549 Wh/L, in weight and volume energy density, respectively. Further, this high energy density LIB with L-CNT offers stable cyclability, which may constitute valuable progress in portable devices and electric vehicle (EV) applications.