A robust and tunable halogen bond organocatalyzed 2-deoxyglycosylation involving quantum tunneling
oleh: Chunfa Xu, V. U. Bhaskara Rao, Julia Weigen, Charles C. J. Loh
| Format: | Article |
|---|---|
| Diterbitkan: | Nature Portfolio 2020-09-01 |
Deskripsi
Halogen bonding (HB) catalysis is rapidly gaining momentum, however, cases of XB activation for challenging bonds formation are rare. Here, the authors show a robust XB catalyzed 2-deoxyglycosylation with broad scope and featuring a quantum tunneling phenomenon in the proton transfer rate determining step.