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Crystal structure and Hirshfeld surface analysis of [2-(1H-benzimidazol-2-yl-κN3)aniline-κN]dichloridozinc(II) N,N-dimethylformamide monosolvate
oleh: Mohd Muslim, Md. Serajul Haque Faizi, Arif Ali, Mohd Afzal, Musheer Ahmad, Necmi Dege, Ashraf Mashrai
Format: | Article |
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Diterbitkan: | International Union of Crystallography 2021-05-01 |
Deskripsi
The title compound, [ZnCl2(C13H11N3)]·C3H7NO, crystallized in the monoclinic crystal system in space group P21/n. The asymmetric unit contains one neutral complex molecule, which consists of a zinc ion, a bidentate ligand, and two chlorido ligands with dimethylformamide monosolvate. The ligand has two moieties, a benzimidazole and an aniline group. The benzimidazole and aniline planes are not coplanar, subtending a dihedral angle of 18.24 (8)°. The Zn(II) ion shows distorted tetrahedral geometry, being coordinated by an imidazole N atom, the aniline N atom, and two chlorido ligands. The packing features N—H...O, N—H...Cl, C—H...Cl hydrogen bonding.