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The effect of waste carbonized eggshell and silicon carbide (SiC) wt.% on the dry sliding wear behavior of AA2014 alloy green composites produced by electromagnetic stir casting method was investigated. The percentage of waste carbonized eggshell particles and SiC particles varied from 2.5% to 12.5%. The tribological behavior of AA2014/waste carbonized eggshell/SiC hybrid green metal matrix composites (MMCs) was investigated on a pin-on-disc apparatus. The weight percentages of waste carbonized eggshell and of SiC, normal load, and sliding speed and distance were taken as input process parameters, and wear rate was taken as a response. Response surface methodology was used to plan and analyze the experiment. Minimum wear rate was found to be 8.89×10−5 mm3/m with desirability one at optimum parameters of 1.75 m/s (sliding velocity), 6.5 (carbonized eggshell wt.%), 34.24 N (normal load), 1219.63 m (sliding distance), and 11 wt.% (SiC wt.%). In the confirmation experiment, the experimental wear rate of the hybrid green MMC at optimum parameters was found to be 9.5×10−5. Results showed that the experimental wear rate and density of the hybrid green MMC were reduced by about 36.66% and 0.35%, respectively, compared with the matrix.