Photochemical Synthesis of Transition Metal-Stabilized Uranium(VI) Nitride Complexes

oleh: Xiaoqing Xin, Iskander Douair, Thayalan Rajeshkumar, Yue Zhao, Shuao Wang, Laurent Maron, Congqing Zhu

Format: Article
Diterbitkan: Nature Portfolio 2022-07-01

Deskripsi

The synthesis and isolation of uranium(VI) nitride complexes remains challenging. Here, the authors report an example of transition metal (TM) stabilized U(VI) nitride complexes, generated via photolysis of azide-bridged U(IV)-TM precursors.