Carbaryl Sorption by Porogen-Treated Banana Pith Carbon

oleh: M. Sathishkumar, J.G. Choi, C.S. Ku, K. Vijayaraghavan, A.R. Binupriya, S.E. Yun

Format: Article
Diterbitkan: SAGE Publications 2008-11-01

Deskripsi

This paper reports the adsorption ability of banana pith activated carbon, with ZnCl 2 as the porogen, towards carbaryl (1-naphthyl- N -methylcarbamate) from aqueous solution. The pH-edge experiments revealed that carbaryl adsorption onto ZnCl 2 -treated banana pith activated carbon (ZTC) was a pH-dependent process with maximum adsorption occurring at pH 11. The adsorption isotherm obtained at pH 11 revealed that ZTC possessed a maximum adsorption capacity of 45.9 mg/g. The adsorption isotherms were well described by the Langmuir and Freundlich models. The kinetic data obtained at different initial carbaryl concentrations were modelled using pseudo-first- and -second-order models. Acetone successfully desorbed carbaryl with a 99.8% elution efficiency.