Crystal structure of 1-methyl-2-methylamino-3-nitro-1H-chromeno[2,3-b]pyridin-5(10aH)-one

oleh: Rajamani Raja, Nataraj Poomathi, Paramasivam T. Perumal, A. SubbiahPandi

Format: Article
Diterbitkan: International Union of Crystallography 2015-11-01

Deskripsi

In the title compound, C14H13N3O4, the pyran ring adopts an envelope conformation with the methine C atom as the flap. The dihedral angle between the benzene and hydropyridine rings is 29.33 (3)°. The methylamine C atom deviates from the plane of its attached ring by 0.380 (5) Å and an intramolecular N—H...O hydrogen bond closes an S(6) ring. In the crystal, weak C—H...O hydrogen bonds and aromatic π–π stacking interactions [centroid–centroid distances vary from 3.6529 (10) to 3.6872 (10) Å] link the molecules, generating a three-dimensional network.