Improving the Performance of Solution−Processed Quantum Dot Light−Emitting Diodes via a HfO<sub>x</sub> Interfacial Layer

oleh: Jun Hyung Jeong, Min Gye Kim, Jin Hyun Ma, Min Ho Park, Hyoun Ji Ha, Seong Jae Kang, Min-Jae Maeng, Young Duck Kim, Yongsup Park, Seong Jun Kang

Format: Article
Diterbitkan: MDPI AG 2022-12-01

Deskripsi

One of the major obstacles in the way of high−performance quantum dot light−emitting diodes (QLEDs) is the charge imbalance arising from more efficient electron injection into the emission layer than the hole injection. In previous studies, a balanced charge injection was often achieved by lowering the electron injection efficiency; however, high performance next−generation QLEDs require the hole injection efficiency to be enhanced to the level of electron injection efficiency. Here, we introduce a solution−processed HfO<sub>x</sub> layer for the enhanced hole injection efficiency. A large amount of oxygen vacancies in the HfO<sub>x</sub> films creates gap states that lower the hole injection barrier between the anode and the emission layer, resulting in enhanced light−emitting characteristics. The insertion of the HfO<sub>x</sub> layer increased the luminance of the device to 166,600 cd/m<sup>2</sup>, and the current efficiency and external quantum efficiency to 16.6 cd/A and 3.68%, respectively, compared with the values of 63,673 cd/m<sup>2</sup>, 7.37 cd/A, and 1.64% for the device without HfO<sub>x</sub> layer. The enhanced light−emitting characteristics of the device were elucidated by X−ray photoelectron, ultra−violet photoelectron, and UV−visible spectroscopy. Our results suggest that the insertion of the HfO<sub>x</sub> layer is a useful method for improving the light−emitting properties of QLEDs.