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Sustainable alternative substrates for advanced applications represent an increasing field of research that attracts the attention of worldwide experts (in accordance with green chemistry principles). In this context, bio-based substances (BBS) isolated from urban composted biowaste were purified and characterized. Additionally, these materials were tested as auxiliaries in advanced oxidizing photocatalytic processes for the abatement of organic contaminants in aqueous medium. Results highlighted the capability of these substances to enhance efficiency in water remediation treatments under mild conditions, favoring the entire light-driven photocatalytic process.