(N-Butyl-N-phenyldithiocarbamato-κS)triphenyltin(IV)
oleh: Nurul Farahana Kamaludin, Ibrahim Baba, Normah Awang, Mohamed Ibrahim Mohamed Tahir, Edward R. T. Tiekink
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2011-05-01 |
Deskripsi
The title compound, [Sn(C6H5)3(C11H14NS2)], features a tetrahedrally coordinated Sn atom, as the dithiocarbamate ligand coordinates in a monodentate fashion. Due to the proximity of the non-coordinating thione S atom, distortions from ideal tetrahedral geometry about the metal atom are evident with the widest C—Sn—S angle being 117.26 (5)°. In the crystal, molecules are linked by C—H...S interactions, which generate helical supramolecular chains along the b axis.