Tetrakis(triphenylphosphane-κP)silver(I) tetrafluoridoborate
oleh: Qi-Ming Qiu, Xin Wang, Qiong-Hua Jin, Xu Huang, Cun-Lin Zhang
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2012-05-01 |
Deskripsi
The title complex, [Ag(C18H15P)4]BF4, was prepared by the reaction of silver(I) tetrafluoridoborate and triphenylphosphane in the presence of 1,2-bis(pyridin-2-yl)ethylene. The AgI atom is tetrahedrally coordinated by four P atoms from triphenylphosphane (PPh3) ligands. Due to symmetry, the tetrafluoridoborate anion is disordered over three positions (each with one third occupancy). The tetrafluoridoborate anion does not coordinate to the AgI atom.