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The identification of load and mutual inductance parameters of a wireless power transfer system can make the mathematical model of the system more accurate, which can effectively avoid system errors due to parameter uncertainties in the implementation of control, and provide theoretical support for system interoperability and high efficiency. This paper uses the two-port theorem and fundamental wave analysis to establish the identification model and obtain the relationship between inverter output current and load and between mutual inductance and load based on the equivalent circuit of a LCC-S magnetically coupled wireless power transfer system. To make the identification results more accurate, a particle swarm optimization algorithm with weights is introduced to transform the parameter identification problem of the system into an optimization problem, which can obtain the identification method of the system load and mutual inductance parameters. Both simulation and experimental results verify the feasibility and effectiveness of the method.