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Photocatalytic enantioselective α-aminoalkylation of acyclic imine derivatives by a chiral copper catalyst
oleh: Bowen Han, Yanjun Li, Ying Yu, Lei Gong
Format: | Article |
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Diterbitkan: | Nature Portfolio 2019-08-01 |
Deskripsi
Copper-based asymmetric photocatalysis has great synthetic potential, however it has been rarely exploited due to challenges inherent to such systems. Here, a chiral bisoxazoline copper catalyst is involved in a SET process, photoredox catalysis, Lewis acid activation and asymmetric induction to construct chiral vicinal diamines.