1-[2-Oxo-5-(trifluoromethoxy)indolin-3-ylidene]-4-[4-(trifluoromethyl)phenyl]thiosemicarbazide

oleh: Humayun Pervez, Mohammad S. Iqbal, Naveeda Saira, Muhammad Yaqub, M. Nawaz Tahir

Format: Article
Diterbitkan: International Union of Crystallography 2010-07-01

Deskripsi

In the title compound, C17H10F6N4O2S, an intramolecular N—H...N hydrogen bonds forms an S(5) ring whereas N—H...O and C—H...S interactions complete S(6) ring motifs. The dihedral angle between the fused ring system and the phenyl ring is 6.68 (8)°. In the crystal, the molecules are dimerized due to N—H...O interactions. π–π interactions are present between the benzene rings [centroid–centroid distance = 3.6913 (15) Å] and between the five membered ring and the trifluoromethyl)phenyl ring [centroids–centroid distance = 3.7827 (16) Å]. One of the trifluoromethoxy F atoms is disordered over two sites with occupancy ratio of 0.76 (3):0.24 (3). The F atoms of the p-trifluoromethyl substituent are disordered over three sets of sites with an occupancy ratio of 0.70 (2):0.152 (11):0.147 (13).