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The decrease of whole protein in synovial fluid, nitrites, uric and lactic acids against the background of the increase of glucose level and C-reactive protein is observed in patients with osteoarthrosis of second synovitis of knee joints (control group), at that, the degree of activity and roentgenological stage of the disease, presence of digital arteritis and the impairment of endocardium influence the integral surfactant condition of the synovial fluid, and the content of whole protein and β2-microglobulin depend accordingly on the indices of its severity and disease progressing, but dynamic interfacial tension, viscous, elastic and viscoelastic adsorption-rheological properties of articular liquor are closely connected with active surface properties.