Di-μ-thiocyanato-κ4N:N-bis({2,4-dibromo-6-[2-(methylamino)ethyliminomethyl]phenolato-κ3N,N′,O}nickel(II))
oleh: Hong-Wei Lin
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2008-02-01 |
Deskripsi
The title complex, [Ni2(C11H11Br2N2O)2(NCS)2], is a thiocyanate-bridged dinuclear nickel(II) complex. The asymmetric unit contains two molecules. Both Ni atoms in each molecule have a square-pyramidal coordination geometry, and each center is bound by one O and two N atoms of one Schiff base ligand and by one N atom of a bridging thiocyanate ligand, which define the basal planes. N atoms from the bridging thiocyanate ligands occupy the apical positions.