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(E)-1-(Pyridin-2-yl)ethanone O-acryloyloxime
oleh: Andrzej Fruziński, Zbigniew Karczmarzyk, Mariusz Mojzych
Format: | Article |
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Diterbitkan: | International Union of Crystallography 2008-04-01 |
Deskripsi
The title compound, C10H10N2O2, was synthesized by the reaction of the oxime of 2-acetylpyridine and 3-bromopropanoyl chloride in the presence of triethylamine. The molecule adopts a nearly planar chain-extended conformation with the oxime group in a trans and the acryloyl group in an s-cis conformation. This conformation is stabilized by an intramolecular C—H...N hydrogen bond. The screw-related molecules are linked into C(9) chains by C—H...O hydrogen bonds.